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1.
Front Psychol ; 14: 1160046, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-37842713

RESUMO

In the university education system, the evaluation and provision of two-way teacher-student feedback are tools within the control function of educational management. Feedback can be defined as the process that takes place in the context of teacher-student interaction during university courses, both individually and in groups, for the development and achievement of the performance of the two actors involved through evaluation, appreciation, support, perception, and teaching. The research aims to develop an innovative feedback tool for the higher education engineering sector to support the improvement of learning outcome-oriented curricula and teaching activities to better meet the learning needs of Gen Z students while being relevant to the labor market and to society in general. The research had a number of subjects: 246 students (67.5% women, 32.5% men) and 7 teachers to whom two feedback instruments were applied (the SKS instrument and the standard instrument of Lucian Blaga University of Sibiu). After testing the four hypotheses, it was observed that the feedback provided by Gen Z is focused on four areas of competence: psychological, pedagogical, education management, and general impression. Each field includes a set of professional and transversal competencies. The SKS (STOP, KEEP, and START) evaluation form is more reliable in evaluating different disciplines than the standard evaluation form by providing a more homogenous type of feedback for each discipline or teacher.

2.
Molecules ; 26(10)2021 May 20.
Artigo em Inglês | MEDLINE | ID: mdl-34065538

RESUMO

New Co(II), Ni(II), and Cu(II) complexes were synthesized with the Schiff base ligand obtained by the condensation of sulfathiazole with salicylaldehyde. Their characterization was performed by elemental analysis, molar conductance, spectroscopic techniques (IR, diffuse reflectance and UV-Vis-NIR), magnetic moments, thermal analysis, and calorimetry (thermogravimetry/derivative thermogravimetry/differential scanning calorimetry), while their morphological and crystal systems were explained on the basis of powder X-ray diffraction results. The IR data indicated that the Schiff base ligand is tridentate coordinated to the metallic ion with two N atoms from azomethine group and thiazole ring and one O atom from phenolic group. The composition of the complexes was found to be of the [ML2]∙nH2O (M = Co, n = 1.5 (1); M = Ni, n = 1 (2); M = Cu, n = 4.5 (3)) type, having an octahedral geometry for the Co(II) and Ni(II) complexes and a tetragonally distorted octahedral geometry for the Cu(II) complex. The presence of lattice water molecules was confirmed by thermal analysis. XRD analysis evidenced the polycrystalline nature of the powders, with a monoclinic structure. The unit cell volume of the complexes was found to increase in the order of (2) < (1) < (3). SEM evidenced hard agglomerates with micrometric-range sizes for all the investigated samples (ligand and complexes). EDS analysis showed that the N:S and N:M atomic ratios were close to the theoretical ones (1.5 and 6.0, respectively). The geometric and electronic structures of the Schiff base ligand 4-((2-hydroxybenzylidene) amino)-N-(thiazol-2-yl) benzenesulfonamide (HL) was computationally investigated by the density functional theory (DFT) method. The predictive molecular properties of the chemical reactivity of the HL and Cu(II) complex were determined by a DFT calculation. The Schiff base and its metal complexes were tested against some bacterial strains (Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and Bacillus subtilis). The results indicated that the antibacterial activity of all metal complexes is better than that of the Schiff base.


Assuntos
Cobalto/química , Cobre/química , Níquel/química , Bases de Schiff/química , Sulfatiazóis/química , Antibacterianos/química , Análise Espectral/métodos
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